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Enhanced activity of bimetallic Fe-Cu catalysts supported on ceria toward water gas shift reaction: synergistic

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1962-1972 doi: 10.1007/s11705-023-2359-z

摘要： Within the “hydrogen chain”, the high-temperature water gas shift reaction represents a key step to improve the H2 yield and adjust the H2/COx ratio to fit the constraints of downstream processes. Despite the commercial application of the high-temperature water gas shift, novel catalysts characterized by higher intrinsic activity (especially at low temperatures), good thermal stability, and no chromium content are needed. In this work, we propose bimetallic iron-copper catalysts supported on ceria, characterized by low active phase content (iron oxide + copper oxide < 5 wt %). Fresh and used samples were characterized by inductively coupled plasma mass spectrometry, X-ray diffraction, nitrogen physisorption, scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy, and temperature programmed reduction in hydrogen to relate physicochemical features and catalytic activity. The sample with iron/copper ≈ 1 and 4 wt % active phase content showed the best catalytic properties in terms of turnover frequency, no methane formation, and stability. Its unique properties were due to both strong iron-copper interaction and strong metal-support interaction, leading to outstanding redox behavior.

关键词： water gas shift     iron     copper     bimetallic catalysts     ceria     hydrogen    

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Catalytic performance of Co-Mo-Ce-K/γ-Al

Yuqiong ZHAO, Yongfa ZHANG

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 457-460 doi: 10.1007/s11705-010-0524-7

摘要： The catalytic performance of Co-Mo-Ce-K/γ-Al O catalyst for the shift reaction of CO in coke oven gas is investigated using X-ray diffraction (XRD) and temperature-programmed reduction (TPR). The results indicate that Ce and K have a synergistic effect on promoting the catalytic activity, and the Co-Mo-Ce-K/γ-Al O catalyst with 3.0 wt-% CeO and 6.0 wt-% K O exhibits the highest activity. CeO favors Co dispersion and mainly produces an electronic effect. TPR characterization results indicate that the addition of CeO -K O in the Co-Mo-Ce-K/γ-Al O catalyst decreases the reduction temperature of active components, and part of octahedrally coordinated Mo transforms into tetrahedrally coordinated Mo , which has a close relationship with the catalytic activity.

关键词： coke oven gas     water gas shift reaction     sulfur-tolerant catalyst     cerium dioxide    

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Potential shift of bacterial community structure and corrosion-related bacteria in drinking water distributionpipeline driven by water source switching

Yue Hu, Ding Dong, Kun Wan, Chao Chen, Xin Yu, Huirong Lin

《环境科学与工程前沿（英文）》 2021年 第15卷 第2期 doi: 10.1007/s11783-020-1320-3

摘要： Abstract • Bacterial release from aged pipe sections under extreme conditions was quantified. • Released bacterial community structure exhibited large variation after transition. • Risks from transition reduced significantly with cleaner source. As a result of pollution in the present water sources, cities have been forced to utilize cleaner water sources. There are few reports regarding the potential shift of bacterial community structure driven by water source switching, especially that of corrosion-related bacteria. Three types of finished water were used for simulation, the polluted source water from the Qiantang and Dongtiaoxi Rivers (China) was replaced by cleaner water from Qiandao Lake (China). Here, we discussed the transition effects through three simulated reactors. The bacterial characteristics were identified using the high-throughput sequencing and heterotrophic plate count method. It was observed that the level of culturable bacteria declined by 2–3 orders of magnitude after water source switching. The bacterial community released from the pipeline reactor was significantly different under different finished water, and it exhibited large variation at the genus level. Porphyrobacter (58.2%) and Phreatobacter (14.5%) clearly replaced Novosphingobium, Aquabacterium, and Cupriavidus as new dominant genera in system A, which could be attributed to the lower carbon and nitrogen content of the new water source. Although corrosion-inhibiting bacteria decreased after switching, they still maintained dominant in three reactors (6.6%, 15.9%, and 19.7%). Furthermore, potential opportunistic pathogens such as Sphingomonas were detected. Our study shows that after transition to a high quality water source, the total culturable bacteria released was in a downtrend, which leads to a great reduction in the risk of bacterial leakage in the produced drinking water.

关键词： Drinking water biosafety     Water source switching     Drinking water distribution system     Transition effects     High-throughput sequencing    

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The impact of different voltage application modes on biodegradation of chloramphenicol and shift of microbial

《环境科学与工程前沿（英文）》 2022年 第16卷 第11期 doi: 10.1007/s11783-022-1576-x

摘要：

● Presented coupled system enhanced biodegradation of antibiotic chloramphenicol.

关键词： Electrical stimulation     Biodegradation     Microbial community     Chloramphenicol    

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Strategic Thinking on Shallow-water Oil and Gas Exploration in Offshore China

Ke-qiang Wu,Jian-yong Xu,Bo Kang

《工程管理前沿（英文）》 2016年 第3卷 第4期   页码 349-355 doi: 10.15302/J-FEM-2016056

摘要： The oil and gas exploration in offshore China has made great achievements, and as the important areas of offshore exploration, the shallow waters contribute most of the oil and gas reserves and production. However, the available area for exploration is diminishing and the cost of exploration is rising. The field changes and ever increasing difficulties of exploration bring new challenges technically and economically. Therefore, for effective exploration of shallow-water oil and gas in offshore China, it is necessary to center on the general requirements of becoming a powerful marine country and the ideas of value exploration, initiate key research projects in the fields of China’s offshore stratigraphic-lithologic reserves, Paleogene reserves, buried-hill reserves, high temperature and pressure reserves and hydrocarbon-rich sags, and form geological theories and explorative technologies of large and medium size oil and gas field in offshore China. The measures regarding the challenges include: (1) Innovating theoretical understanding and optimizing new exploration fields, (2) developing technical capabilities and improving the success rate of exploration, and (3) enhancing management level and deepening value exploration.

关键词： offshore China     shallow-water oil and gas exploration     strategic thinking     challenge     countermeasure    

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南海北部深水区油气勘探进展与未来展望

米立军 ,周守为 ,谢玉洪 ,张功成 ,杨海长

《中国工程科学》 2022年 第24卷 第3期   页码 58-65 doi: 10.15302/J-SSCAE-2022.03.007

摘要：

加大油气勘探开发力度，减少石油和天然气对外依存度，保障国家能源安全是关系国家经济社会发展的全局性、战略性问题。“十一五”以来，中国海洋石油集团有限公司在南海北部深水领域持续加强基础研究，加快技术创新和加大勘探投入，相继获得一批重大油气勘探发现。本文阐述了五项重大勘探地质理论认识和两项勘探技术创新成果，探讨了深水油气勘探将要面临的挑战和应对策略，展望了南海北部深水区中深层、潜山及岩性圈闭三大领域的勘探前景。研究指出，南海北部陆缘深水区的拆离作用控制了珠江口盆地和琼东南盆地大型凹陷的形成，发育了湖相、海陆过渡相和海相三套规模烃源岩；高‒ 变地温控制凹陷烃源岩快速生烃，建立了琼东南盆地深水区大型轴向峡谷水道油气成藏模式、白云凹陷深水区深水扇天然气晚期成藏模式和深水区“断‒ 脊”联控油气差异聚集成藏模式。同时自主创新研发了立体震源激发和“犁形”缆接收的宽频采集处理技术。在多项地质理论认识和创新技术的指导下，发现以“深海一号”（陵水17-2）等为代表的一批大中型气田，对于保障粤港澳大湾区能源供应、促进海南自贸区（港）能源绿色发展、推动我国油气增储上产具有重要意义。

关键词： 南海北部；深水区；油气勘探；深水天然气    

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Coordinated shift control of nonsynchronizer transmission for electric vehicles based on dynamic tooth

《机械工程前沿（英文）》 2021年 第16卷 第4期   页码 887-900 doi: 10.1007/s11465-021-0653-3

摘要： Multispeed transmissions can enhance the dynamics and economic performance of electric vehicles (EVs), but the coordinated control of the drive motor and gear shift mechanism during gear shifting is still a difficult challenge because gear shifting may cause discomfort to the occupants. To improve the swiftness of gear shifting, this paper proposes a coordinated shift control method based on the dynamic tooth alignment (DTA) algorithm for nonsynchronizer automated mechanical transmissions (NSAMTs) of EVs. After the speed difference between the sleeve (SL) and target dog gear is reduced to a certain value by speed synchronization, angle synchronization is adopted to synchronize the SL quickly to the target tooth slot’s angular position predicted by the DTA. A two-speed planetary NSAMT is taken as an example to carry out comparative simulations and bench experiments. Results show that gear shifting duration and maximum jerk are reduced under the shift control with the proposed method, which proves the effectiveness of the proposed coordinated shift control method with DTA.

关键词： electric vehicle     nonsynchronizer automated mechanical transmission (NSAMT)     planetary gear     coordinated shift control     dynamic tooth alignment    

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Extension of pilot tests of cyanide elimination by ozone from blast furnace gas washing water through

Ismael Matino, Valentina Colla, Teresa A. Branca

《化学科学与工程前沿（英文）》 2018年 第12卷 第4期   页码 718-730 doi: 10.1007/s11705-018-1771-2

摘要：

For improving wastewater quality, one of the dare of steelworks is reducing cyanide in wastewater of gas washing treatment of blast furnaces. Costs of existing treatments, stringent environmental regulations and changeable composition of water from gas treatment, have led to study how available treatments can be modified and to examine new ones. Ozonation is one of cyanide treatments, tested within a European project. A process model was set up with Aspen Plus®, to assess operating conditions and wastewater distinctive characteristics and to demonstrate treatment robustness. Process was modeled by theoretical reactors, taking into account all more affecting reactions. A genetic algorithm was exploited to find kinetic parameters of these reactions. After validation, the model was used to analyse scenarios, by considering also real contexts. Pilot tests were extended, process knowledge was enhanced and suggestions were obtained. To promote cyanide removal with ozone, temperature and pH values were 30°C and 10, respectively. With an ozone (mg/h)/water (L/h) ratio of 100 mg/L, batch mode ensure reaching cyanide regulation limit (0.2 mg/L) after maximum 4.5 h, if initial amount was less than 20 mg/L. Higher removal was obtained than in continuous mode due to constraints related to this last run. Higher wastewater contamination needed further time and more ozone.

关键词： blast furnace     cyanide removal     gas washing water     modeling and simulation     ozonation    

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Simultaneous analysis of five taste and odor compounds in surface water using solid-phase extractionand gas chromatography-mass spectrometry

Wenfeng SUN, Ruibao JIA, Baoyu GAO

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 66-74 doi: 10.1007/s11783-010-0257-3

摘要： In this paper, a method using solid-phase extraction (SPE) and gas chromatography-mass spectrometry (GC-MS) was developed to simultaneously analyze five taste and odor compounds in surface water, i.e., 2-methylisoborneol (2-MIB), 2,4,6-trichloroanisole (TCA), 2-isopropyl-3-methoxy pyrazine (IPMP), 2-isobutyl-3-methoxy pyrazine (IBMP), and -1,10-dimethyl- -9-decalol (geosmin, GSM). The mass spectrometry was operated in selective ion monitoring (SIM) mode. Three kinds of SPE columns and three eluting solvents were compared, the C18 column was chosen as optimum SPE column, and methanol was chosen as the optimum eluting solvent. It was found that the method showed good linearity in the range of 1–200 ng·L and gave detection limits of 0.5–1.5 ng·L for individual compounds. Good recoveries (93.5%–108%) and relative standard deviations (1.58%–7.31%) were also obtained. Additionally, concentrations of these taste and odor compounds in Jinan’s surface and drinking water were analyzed by applying this method, and the results showed that GSM and 2-MIB were the dominant taste and odor compounds in Jinan’s raw water.

关键词： solid-phase extraction (SPE)     gas chromatography-mass spectrometry (GC-MS)     taste and odor compounds     surface water     micropollutant    

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Determination of selected semi-volatile organic compounds in water using automated online solid-phaseextraction with large-volume injection/gas chromatography/mass spectrometry

Yongtao LI, Christina L. MCCARTY, Ed J. GEORGE

《环境科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 417-425 doi: 10.1007/s11783-011-0310-x

摘要： A rapid, sensitive, and cost-effective analytical method was developed for the analysis of selected semi-volatile organic compounds in water. The method used an automated online solid-phase extraction technique coupled with programmed-temperature vaporization large-volume injection gas chromatography/mass spectrometry. The water samples were extracted by using a fully automated mobile rack system based on x-y-z robotic techniques using syringes and disposable 96-well extraction plates. The method was validated for the analysis of 30 semi-volatile analytes in drinking water, groundwater, and surface water. For a sample volume of 10 mL, the linear calibrations ranged from 0.01 or 0.05 to 2.5μg·L , and the method detection limits were less than 0.1μg·L . For the reagent water samples fortified at 1.0μg·L and 2.0?μg·L , the obtained mean absolute recoveries were 70%–130% with relative standard deviations of less than 20% for most analytes. For the drinking water, groundwater, and surface water samples fortified at 1.0μg·L , the obtained mean absolute recoveries were 50%–130% with relative standard deviations of less than 20% for most analytes. The new method demonstrated three advantages: 1) no manipulation except the fortification of surrogate standards prior to extraction; 2) significant cost reduction associated with sample collection, shipping, storage, and preparation; and 3) reduced exposure to hazardous solvents and other chemicals. As a result, this new automated method can be used as an effective approach for screening and/or compliance monitoring of selected semi-volatile organic compounds in water.

关键词： automated solid-phase extraction     programmed-temperature vaporization     large-volume injection     gas chromatography/mass spectrometry     semi-volatile organic compounds     water analysis    

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Energy shift: decline of easy oil and restructuring of geo-politics

Oliver R. INDERWILDI,David A. KING

《能源前沿（英文）》 2016年 第10卷 第3期   页码 260-267 doi: 10.1007/s11708-016-0416-8

摘要： This paper critically assesses the geopolitical and geo-economic impact of novel fuel resources on both resource exporters and importers. Presently, very strong political and economic forces drive the utilisation of domestic, unconventional oil and gas recovery in the West as these enhance energy security and ease balance of payment issues. The additional capacity generated by this trend has, supported by other effects such as Saudi Arabia’s decision to maintain current production, triggered a significant reduction of oil prices. Consequently, it is now oil exporters that struggle with the balance of payment issues and often these countries base their fiscal budget completely on fossil fuel revenues. In fact, these unconventional resources help turn the tide while oil exporters are now politically significantly weakened due to the increased energy sufficiency of the West. The catch is that the extraction of unconventional types of oil has many environmental implications. So, internalising the environmental externalities have to be considered. This paper, therefore, assesses, next to geopolitics and geo-economics, the environmental implications of this trend.

关键词： energy security     climatic change     geo-economics     geopolitics     unconventional resources     macroeconomics    

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世界油气上游国际合作的形势和机会

童晓光

《中国工程科学》 2011年 第13卷 第4期   页码 15-19

摘要：

指出中国利用国外油气的必要性，重点分析了伊拉克、伊朗、巴西、加拿大、委内瑞拉和北美油气上游合作的机会及世界油气国际合作的合同变化趋势，提出了当前扩大油气上游国际合作的主要方向。

关键词： 油气上游国际合作     伊拉克     深水油气勘探     重油和油砂     非常规天然气    

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Construction engineering management culture shift: Is the lowest tender offer dead?

Eric SCHEEPBOUWER, Douglas D. GRANSBERG, Carla Lopez del PUERTO

《工程管理前沿（英文）》 2017年 第4卷 第1期   页码 49-57 doi: 10.15302/J-FEM-2017014

摘要： The procurement of public construction projects must walk a fine line between the corruption of state officials and collusion of contractors. The method of awarding projects to the lowest responsible tenderer was originally implemented to guard against corruption of state officials. However, an investigation of the construction industry in the Canadian province of Quebec showed that lowest-tender-offer procurement gave rise to collusion of companies tendering for the contracts. Alternatively, best-value procurement has been used for decades, but here problems arise owing to the necessity of subjective judging of measures other than price to compare bids, giving rise to time- and money-consuming protests. The paper proposes a compelling argument that the construction engineering management (CEM) culture should refocus its efforts on enhancing project cost certainty rather than merely searching for means to design a project in a manner that produces the lowest initial cost, and awards the construction to the lowest tender offer that focuses on cost savings during the project development and delivery process. The difference in the two approaches is subtle but extremely important. To make the transition, the engineering management tools must be advanced to the next level. This means that all project control tools for managing cost, schedule, and technical scope must be transformed from working in the deterministic mode to the stochastic mode, thus making the probability of completing the project within or below its official budget the primary decision criterion. To do so, CEMs must accept that there is a benefit in paying more for an alternative that increases cost certainty for the entire project. The authors of this paper hope that it will provide the grist for a more general dialog across all industry sectors where engineering management is practiced.

关键词： cost certainty     lowest responsible bid     best value     public procurement     construction engineering management culture    

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Seasonal microbial community shift in a saline sewage treatment plant

Qingmei YAN, Xuxiang ZHANG, Tong ZHANG, Herbert H P FANG

《环境科学与工程前沿（英文）》 2011年 第5卷 第1期   页码 40-47 doi: 10.1007/s11783-011-0304-8

摘要： Activated sludge was monthly sampled from a saline sewage treatment plant of Hong Kong (China) during June 2007 to May 2008 to analyze the microbial community shift along with environmental variations using denaturing gradient gel electrophoresis of polymerase chain reaction amplified 16S rDNA fragments. Environmental changes resulted into a seasonal microbial community shift characterized by alterations in species number and abundance in the sewage treatment plant. Correspondence analysis and cluster analysis on community structure profile showed that the 12 monthly samples fell into four groups, which is in accordance with season changing in Hong Kong. Canonical correspondence analysis revealed that and posed more significant effects on community structure than total phosphorus and total nitrogen, respectively. Compared with sludge retention time, influent total phosphorus had an inverse effect on the community structure shift, and chemical oxygen demand and showed a similar effects. Results of this study may contribute to the development of new knowledge involving the microbial community shift in sewage treatment plants.

关键词： sewage treatment plants     polymerase chain reaction (PCR)     denaturing gradient gel electrophoresis (DGGE)     canonical correspondence analysis     correspondence analysis    

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凝析气藏的经济开采模式

刘廷元

《中国工程科学》 2001年 第3卷 第3期   页码 85-91

摘要：

液态凝析油是凝析气藏的重要产品，它的开采应该是有效而经济的。介绍了国外近20 a来在凝析气藏开采技术领域的各种经济模式，包括回注φd=75%干气、自流回注、注N2、注水、水气交替注和注CO2等开采模式。研究结果表明，这些开采模式同传统的降压开采方法相比，能够有效地适应地面-地下的各种复杂情况。

关键词： 凝析气藏     开采模式     注气     注氮     注水     注二氧化碳     经济    

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标题 作者 时间 类型 操作

Enhanced activity of bimetallic Fe-Cu catalysts supported on ceria toward water gas shift reaction: synergistic

期刊论文

Catalytic performance of Co-Mo-Ce-K/γ-Al

Yuqiong ZHAO, Yongfa ZHANG

期刊论文

Potential shift of bacterial community structure and corrosion-related bacteria in drinking water distributionpipeline driven by water source switching

Yue Hu, Ding Dong, Kun Wan, Chao Chen, Xin Yu, Huirong Lin

期刊论文

The impact of different voltage application modes on biodegradation of chloramphenicol and shift of microbial

期刊论文

Strategic Thinking on Shallow-water Oil and Gas Exploration in Offshore China

Ke-qiang Wu,Jian-yong Xu,Bo Kang

期刊论文

南海北部深水区油气勘探进展与未来展望

米立军 ,周守为 ,谢玉洪 ,张功成 ,杨海长

期刊论文

Coordinated shift control of nonsynchronizer transmission for electric vehicles based on dynamic tooth

期刊论文

Extension of pilot tests of cyanide elimination by ozone from blast furnace gas washing water through

Ismael Matino, Valentina Colla, Teresa A. Branca

期刊论文

Simultaneous analysis of five taste and odor compounds in surface water using solid-phase extractionand gas chromatography-mass spectrometry

Wenfeng SUN, Ruibao JIA, Baoyu GAO

期刊论文

Determination of selected semi-volatile organic compounds in water using automated online solid-phaseextraction with large-volume injection/gas chromatography/mass spectrometry

Yongtao LI, Christina L. MCCARTY, Ed J. GEORGE

期刊论文

Energy shift: decline of easy oil and restructuring of geo-politics

Oliver R. INDERWILDI,David A. KING

期刊论文

世界油气上游国际合作的形势和机会

童晓光

期刊论文

Construction engineering management culture shift: Is the lowest tender offer dead?

Eric SCHEEPBOUWER, Douglas D. GRANSBERG, Carla Lopez del PUERTO

期刊论文

Seasonal microbial community shift in a saline sewage treatment plant

Qingmei YAN, Xuxiang ZHANG, Tong ZHANG, Herbert H P FANG

期刊论文

凝析气藏的经济开采模式

刘廷元

期刊论文